4-(3-Fluoro-4-methylanilino)-2-methylidene-4-oxobutanoic acid

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4-(3-Fluoro-4-methyl­anilino)-2-methyl­idene-4-oxo­butanoic acid

The title compound, C12H12FNO3, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. The dihedral angle between the mean planes of the 3-fluoro-4-methyl-phenyl ring and the oxo-amine group is 25.7 (7)° in mol-ecule A and 71.3 (7)° in mol-ecule B, while the mean plane of the 2-methyl-idene-4-oxo-butanoic acid group is twisted by 76.2 (1)° from that of the oxo-amine grou...

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4-(9,10-Dioxo-9,10-dihydro­anthracen-1-yl)-4-oxobutanoic acid

In the title compound, C(18)H(12)O(5), the anthracene moiety is almost planar (r.m.s. deviation = 0.0399 Å). In the crystal, mol-ecules are linked to each other by inter-molecular O-H⋯O and weak C-H⋯O hydrogen bonds.

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2-(2-Fluoro-4-nitro­phen­oxy)-3-nitro­pyridine

In the title compound, C11H6FN3O5, the dihedral angle between the aromatic rings is 72.4 (3)°. The NO2 groups form dihedral angles of 40.8 (2) and 4.8 (2)°, respectively, with the attached pyridine and benzene rings. The crystal structure features π-π stacking between centrosymmetrically related pairs of pyridine rings [centroid-centroid separation = 3.800 (3) Å].

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3-Fluoro-4-(4-hy­droxy­phen­oxy)benzonitrile

The title compound, C(13)H(8)FNO(2), was synthesized from 3,4-difluoro-benzonitrile and hydro-quinone. The dihedral angle between the two aromatic rings is 70.9 (2)°. In the crystal structure, mol-ecules are linked by O-H⋯N hydrogen bonds, forming zigzag chains.

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3-Fluoro-4-nitro­phenyl 4-methyl­benzene­sulfonate

In the title compound, C(13)H(10)FNO(5)S, the dihedral angle between the benzene rings is 47.63 (14)°. In the crystal, π-π stacking occurs between nearly parallel benzene rings of adjacent mol-ecules, the centroid-centroid distance being 3.7806 (16) Å. Weak inter-molecular C-H⋯O hydrogen bonding is also present in the crystal structure.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2013

ISSN: 1600-5368

DOI: 10.1107/s160053681302998x